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Inorganic Chemistry Division

LOGO

Manager

Barbara Barszcz, Ph.D., Sc.D., Associate Professor (Barbara.Barszcz@ujk.edu.pl)

Staff

Ph.D. students

Technical assistant

Specialization

Synthesis and studies of coordination compounds with selected metal ions of importance in chemistry, biology and medicine.

Scope of investigations

Manuscripts

  1. M. Kowalik, J. Masternak, B. Barszcz, Recent research trends on bismuth compounds in cancer chemo- and radiotherapy. Current Medicinal Chemistry (2017)
    doi: 10.2174/0929867324666171003113540.
  2. M. Puszyńska-Tuszkanow, W. Zierkiewicz, T. Grabowski, M. Daszkiewicz, G. Maciejewska, A. Adach, K. Kucharska-Ziembicka, J. Wietrzyk, Magnesium cinnamate complex, [Mg(cinn)2(H2O)2]n; structural, spectroscopic, thermal, biological and pharmacokinetical characteristics. Journal of Molecular Structure 1134, 199-207 (2017).
  3. A. Adach, Review: an overview of recent developments in coordination chemistry of polypyrazolylmethylamines. Complexes with N-scorpionate ligands created in situ from pyrazole derivatives and zerovalent metals. Journal of Coordination Chemistry 70, 757-779 (2017).
  4. I. Goszewska, D. Giziński, M. Zienkiewicz-Machnik, D. Lisovytskiy, K. Nikiforov, J. Masternak, A. Śrębowata, J. Sá, A novel nano-palladium catalyst for continuous-flow chemoselective hydrogenation reactions. Catalysis Communications 94, 65-68 (2017).
  5. D. Giziński, I. Goszewska, M. Zieliński, D. Lisovytskiy, K. Nikiforov, J. Masternak, M. Zienkiewicz-Machnik, A. Śrębowata, J. Sá, Chemoselective flow hydrogenation of α,β – unsaturated aldehyde with nano-nickel. Catalysis Communications 98, 17-21 (2017).
  6. J. Masternak, M. Zienkiewicz-Machnik, M. Kowalik, A. Jabłońska-Wawrzycka, P. Rogala, A. Adach, B. Barszcz, Recent advances in coordination chemistry of metal complexes based on nitrogen heteroaromatic alcohols. Synthesis, structures and potential applications. Coordination Chemistry Reviews 327-328, 242-270 (2016).
  7. P. Rogala, A. Jabłońska-Wawrzycka, K. Kazimierczuk, A. Borek, A. Błażejczyk, J. Wietrzyk, B. Barszcz, Synthesis, crystal structure and cytotoxic activity of ruthenium(II) piano-stool complex with N,N-chelating ligand. Journal of Molecular Structure 1126, 74-82 (2016).
  8. M. Zienkiewicz-Machnik, J. Masternak, K. Kazimierczuk, B. Barszcz, Structural analysis and physico-chemical characterization of mononuclear manganese(II) and polynuclear copper(II) complexes with pyridine-based alcohol. Journal of Molecular Structure 1126, 37-46 (2016).
  9. A. Jabłońska-Wawrzycka, P. Rogala, G. Czerwonka, M. Hodorowicz, K. Stadnicka, Zinc(II) complexes with heterocyclic ether, acid and amide. Crystal structure, spectral, thermal and antibacterial activity studies. Journal of Molecular Structure 1105, 357-369 (2016).
  10. A. Adach, M. Daszkiewicz, M. Tyszka-Czochara, A family of complexes with N-scorpionate-type and other N-donor ligands obtained in situ from pyrazole derivative and zerovalent cobalt. Physicochemical and cytotoxicity studies. RSC Advances 6, 44070-44079 (2016).
  11. A. Adach, M. Daszkiewicz, Experimental and theoretical studies on the structure and spectroscopic properties of Co(III) and Co(II) complexes with 2-aminopyrimidine. Inorganica Chimica Acta 445, 87-95 (2016).
  12. H. Fałtynowicz, M. Daszkiewicz, R. Wysokiński, A. Adach, M. Cieślak-Golonka, Ni(II) complex with sarcosine derived from in situ generated ligand: structural, spectroscopic, and DFT studies. Structural Chemistry 26, 1555-1563 (2015).
  13. A. Adach, M. Daszkiewicz, M. Tyszka-Czochara, B. Barszcz, New oxovanadium(IV) complexes with pincer ligand obtained in situ: experimental and theoretical studies on the structure, spectroscopic properties and antitumor activity. RSC Advances 5, 85470-85479 (2015).
  14. A. Adach, M. Daszkiewicz, B. Barszcz, Experimental and theoretical studies on the structure and spectroscopic properties of N-scorpionate complexes obtained from metallic cobalt in a one pot synthesis. Polyhedron 95, 60-68 (2015).
  15. A. Jabłońska-Wawrzycka, P. Rogala, G. Czerwonka, M. Hodorowicz, K. Stadnicka, Zinc(II) complexes with heterocyclic ether, acid and amide. Crystal structure, spectral, thermal and antibacterial activity studies. Journal of Molecular Structure 1105, 357-369 (2015).
  16. J. Masternak, B. Barszcz, M. Hodorowicz, O.V. Khavryuchenko, A. Majka, Synthesis and physicochemical characterization of two lead(II) complexes with O-, N-donor ligands. Lone pair functionality and crystal structure. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 136, 1998-2007 (2015).
  17. M. Zienkiewicz, A. Jabłońska-Wawrzycka, J. Szlachetko, Y. Kayser, K. Stadnicka, W. Sawka-Dobrowolska, J. Jezierska, B. Barszcz, J. Sá, Effective catalytic disproportionation of aqueous H2O2 with di- and mono-nuclear manganese(II) complexes containing pyridine alcohol ligands. Dalton Trans., 43, 8599–8608 (2014).
  18. J. Masternak, B. Barszcz, W. Sawka-Dobrowolska, J. Wietrzyk, J. Jezierska, M. Milczarek, An efficient process to directly convert 1-hydroxymethyl-3,5-dimethylpyrazole to Cd(II) complexes via C-N bond creation: cytotoxicity and factors controlling the structures. RSC Adv., 4, 43962-43972 (2014).
  19. A. Jabłońska-Wawrzycka, B. Barszcz, M. Zienkiewicz, M. Hodorowicz, J. Jezierska, K. Stadnicka, Ł. Lechowicz, W. Kaca, Eight- and six-coordinated Mn(II) complexes of heteroaromatic alcohol and aldehyde: Crystal structure, spectral, magnetic, thermal and antibacterial activity studies. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 129, 632–642 (2014).
  20. G. Czerwonka, M. Arabski, S. Wąsik, A. Jabłońska-Wawrzycka, P. Rogala, W. Kaca, Morphological changes in Proteus mirabilis O18 biofilm under the influence of a urease inhibitor and a homoserine lactone derivative. Archives of Microbiology 196, 169-177 (2014).
  21. A. Adach, M. Daszkiewicz, M. Cieślak-Golonka, T. Misiaszek, D. Grabka, In situ synthesis of scorpion-like complexes isolated from the system containing zerovalent nickel. Polyhedron 78, 31–39 (2014).
  22. A. Adach, M. Daszkiewicz, M. Duczmal, Z. Staszak, Cobalt(II) complex containing two-ring scorpionate-like ligands formed in situ. Studies on the [Co0-1-hydroxymethyl-3,5-dimethylpyrazole-MoO3-NH4I] system. Inorganic Chemistry Communications 35, 22–26 (2013).
  23. M. Zienkiewicz, J. Szlachetko, Ch. Lothschütz, M. Hodorowicz, A. Jabłońska-Wawrzycka, J. Sá, B. Barszcz,A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water. Dalton Trans., 42, 7761-67 (2013).
  24. A. Jabłońska-Wawrzycka, P. Rogala, S. Michałkiewicz, M. Hodorowicz, B. Barszcz, Ruthenium complexes in different oxidation states: synthesis, crystal structure, spectra and redox properties. Dalton Trans., 42, 6092-6101 (2013).
  25. B. Barszcz, J. Masternak, M. Hodorowicz, E. Matczak-Jon, A. Jabłońska-Wawrzycka, K. Stadnicka, M. Zienkiewicz, K. Królewska, J. Kaźmierczak-Barańska; Synthesis, crystal structure and NMR investigation of novel Ca(II) complexes with heterocyclic alcohol, aldehyde and carboxylate ligands. Evaluation of Ca(II) and Cd(II) analogues for anticancer activity. Inorganica Chimica Acta 399, 85-94 (2013).
  26. B. Barszcz, J. Masternak, W. Sawka-Dobrowolska; Assembling novel Cd(II) complexes with multidentate nitrogen donors ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonia thiocyanate. Dalton Trans.,42, 5960-5964 (2013).
  27. A. Puszko, A. Kochel, J. Wietrzyk, B. Filip-Psurska, J. Jezierska, M. Puszyńska-Tuszkanow, Z. Staszak, A. Adach, J. Lorenc, M. Cieślak-Golonka, Structure–activity relationship disturbed by a solvolytic process: Study on the [Cu(II)-4-nitropyridine N-oxide derivative] system. Polyhedron 50, 146-153 (2013).
  28. A. Adach, M. Daszkiewicz, M. Cieślak-Golonka, Cobalt(II) scorpionate-like complexes obtained from in situ synthesized ligand created in [Co(0)–1-hydroxymethyl-3,5-dimethylpyrazole–VOSO4–NH4SCN] system. Polyhedron 47, 104-111 (2012).
  29. A. Jabłońska–Wawrzycka, M. Zienkiewicz, B. Barszcz, P. Rogala, Thermoanalytical study of selected transition bivalent metal complexes with 5-carbaldehyde-4-methylimidazole. Journal of Thermal Analysis and Calorimetry 109, 735–743 (2012).
  30. B. Barszcz, J. Masternak, M. Hodorowicz, A. Jabłońska-Wawrzycka, Cadmium(II) and calcium(II) complexes with N,O-bidentate ligands derived from pyrazinecarboxylic acid. Thermal data and crystal structure correlation. Journal of Thermal Analysis and Calorimetry 108, 971-97 (2012).
  31. A. Jabłońska–Wawrzycka, K. Stadnicka, J. Masternak, M. Zienkiewicz, Novel eight-coordinated Cd(II) complexes with two homologous pyridine alcohols. Crystal structure, spectroscopic and thermal properties. Journal of Molecular Structure 1012, 94-104 (2012).
  32. A. Jabłońska-Wawrzycka, M. Zienkiewicz, M. Hodorowicz, P. Rogala, B. Barszcz, Thermal behavior of manganese(II) complexes with pyridine-2,3-dicarboxylic acid. Journal of Thermal Analysis and Calorimetry 110, 1367-1376 (2012).
  33. A. Puszko, A. Brzuszkiewicz, J. Jezierska, A. Adach, J. Wietrzyk, B. Filip, M. Pełczyńska, M. Cieślak-Golonka, Systematic coordination chemistry and cytotoxicity of copper(II) complexes with methyl substituted 4-nitropyridine N-oxides. Journal of Inorganic Biochemistry 105, 1109-1114 (2011).
  34. A. Jabłońska–Wawrzycka, M. Zienkiewicz, B. Barszcz, Zastosowanie analizy termicznej do badania związków koordynacyjnych. Aparatura badawcza i dydaktyczna 16, 99–105 (2011).
  35. A. Adach, M. Daszkiewicz, B. Barszcz, Synthesis, X-ray structure, and spectroscopic investigation of new Co(II)/Cd(II) complexes formed via the reaction of 1-hydroxymethyl-3,5-dimethylpyrazole and Co0, CdCl2, NH4I. Structural Chemistry, 21, 331-336 (2010).
  36. M. Puszyńska-Tuszkanow, M. Daszkiewicz, G. Maciejewska, A. Adach, M. Cieślak-Golonka, Interaction of hydantoins with transition metal ions: synthesis, structural, spectroscopic, thermal and magnetic properties of [M(H2O)4(phenytoinate)2] Ni(II), Co(II). Structural Chemistry 21, 315-32 (2010).
  37. A. Puszko, A. Krojcer, M. Pełczyńska, J. Wietrzyk, M. Cieślak-Golonka, J.Jezierska, A. Adach, M. Kubiak, Mononuclear cooper(II) nitrato with methyl-substitued 4-nitropyridyne N-oxide. Physicochemical and cytotoxic characteristics. Journal of Inorganic Biochemistry 104, 153-160 (2010).
  38. A. Adach, M. Daszkiewicz, B. Barszcz, M. Cieślak- Golonka, G. Maciejewska, Redox processes as a route for the formation of an unusual structure of the Co(II)/Zn(II) complexes isolated from the system: [Co(0)/Zn(II)-1-hydroxymethyl-3,5-dimethylpyrazole]. Inorganic Chemistry Communications 13, 361-364 (2010).
  39. B. Barszcz, M. Hodorowicz, A. Jabłońska-Wawrzycka, J. Masternak, W. Nitek, K. Stadnicka, Comparative study on Cd(II) and Ca(II) model complexes with pyridine-2,3-dicarboxylic acid. Synthesis, crystal structure and spectroscopic investigation. Polyhedron 29, 1191-1200 (2010).
  40. B. Barszcz, J. Masternak, W. Surga, Thermal properties of Ca(II) and Cd(II) complexes of pyridinedicrboxylates. Correlation with crystal structures. Journal of Thermal Analysis and Calorimetry 101, 633-639 (2010).
  41. E. Kowalska, E. Czerwosz, M. Kozłowski, W. Surga, J. Radomska, H. Wronka, Structural, thermal, and electrical properties of carbonaceous films containing palladium nanocrystals. Journal of Thermal Analysis and Calorimetry 101, 737-742 (2010).
  42. S. De Angelis Curtis, M. Kubiak, K. Kurdziel, S. Materazzi, S. Vecchio, Crystal structure and thermoanalytical study of a cadmium(II) complex with 1-allylimidazole. J. Anal. Appl. Pyrolysis 87, 175-179 (2010).
  43. S. De Angelis Curtis, K. Kurdziel, S. Materazzi, S. Vecchio, Crystal structure and thermoanalytical study of cobalt(II) and nickel(II) complexes with 2,2’-bis-(4,5-dimethylimidazole). Thermochimica Acta 510, 75-81 (2010).

Field of didactic activity

  1. Subjects for students of chemistry
  2. Subject for students of biotechnology
  3. Subject for students of biology
  4. Subject for students of environmental protection